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UV-Visible Spectroscopy

4. The Importance of Conjugation. A comparison of the absorption spectrum of 1-pentene, λ max = 178 nm, with that of isoprene (above) clearly demonstrates the importance of chromophore conjugation. Further evidence of this effect is shown below. The spectrum on the left illustrates that conjugation of double and triple bonds also shifts the absorption maximum to longer wavelengths.

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Cold enough to freeze the balls off a brass

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Determination of (a) Wavelength of maximum absorbance ...

The wavelength at which a substance shows maximum absorbance is called absorption maximum or λmax. The value of λmax is important for several reasons. This wavelength is characteristic of each compound It provides information on the electronic structure of the analyte It ensures highest sensitivity and minimize deviations from Beer's Law.